Preheat your oven to 350°F (175°C) and grease and flour two 9-inch round cake pans.
In a medium-sized bowl, whisk together the flour, baking powder, baking soda, and salt.
In a large mixing bowl, cream together the butter and sugar until light and fluffy.
Add the eggs one at a time, beating well after each addition, then mix in the vanilla extract.
In a separate bowl, combine the milk and sour cream until smooth.
Gradually add the dry ingredients to the butter mixture, alternating with the milk-sour cream mixture, and fold in the melted white chocolate.
Divide the batter between the prepared cake pans and bake for 25-30 minutes or until a toothpick comes out clean.